- Home
- Search Results
- Page 1 of 1
Search for: All records
-
Total Resources1
- Resource Type
-
00010
- Availability
-
10
- Author / Contributor
- Filter by Author / Creator
-
-
Grass, Amanda (1)
-
Groysman, Stanislav (1)
-
Kulathungage, Lakshani Wathsala (1)
-
Wannipurage, Duleeka (1)
-
Ward, Cassandra L. (1)
-
Yousif, Maryam (1)
-
#Tyler Phillips, Kenneth E. (0)
-
#Willis, Ciara (0)
-
& Abreu-Ramos, E. D. (0)
-
& Abramson, C. I. (0)
-
& Abreu-Ramos, E. D. (0)
-
& Adams, S.G. (0)
-
& Ahmed, K. (0)
-
& Ahmed, Khadija. (0)
-
& Akcil-Okan, O. (0)
-
& Akuom, D. (0)
-
& Aleven, V. (0)
-
& Andrews-Larson, C. (0)
-
& Archibald, J. (0)
-
& Arnett, N. (0)
-
- Filter by Editor
-
-
null (1)
-
& Spizer, S. M. (0)
-
& . Spizer, S. (0)
-
& Ahn, J. (0)
-
& Bateiha, S. (0)
-
& Bosch, N. (0)
-
& Brennan K. (0)
-
& Brennan, K. (0)
-
& Chen, B. (0)
-
& Chen, Bodong (0)
-
& Drown, S. (0)
-
& Ferretti, F. (0)
-
& Higgins, A. (0)
-
& J. Peters (0)
-
& Kali, Y. (0)
-
& Ruiz-Arias, P.M. (0)
-
& S. Spitzer (0)
-
& Spitzer, S. (0)
-
& Spitzer, S.M. (0)
-
(submitted - in Review for IEEE ICASSP-2024) (0)
-
-
Have feedback or suggestions for a way to improve these results?
!
Note: When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher.
Some full text articles may not yet be available without a charge during the embargo (administrative interval).
What is a DOI Number?
Some links on this page may take you to non-federal websites. Their policies may differ from this site.
-
null (Ed.)Reaction of LiOC t Bu 2 Ph with TlPF 6 forms the dimeric Tl 2 (OC t Bu 2 Ph) 2 complex, a rare example of a homoleptic thallium alkoxide complex demonstrating formally two-coordinate metal centers. Characterization of Tl 2 (OC t Bu 2 Ph) 2 by 1 H and 13 C NMR spectroscopy and X-ray crystallography reveals the presence of two isomers differing by the mutual conformation of the alkoxide ligands, and by the planarity of the central Tl–O–Tl–O plane. Tl 2 (OC t Bu 2 Ph) 2 serves as a convenient precursor to the formation of old and new [M(OC t Bu 2 Ph) n ] complexes (M = Cr, Fe, Cu, Zn), including a rare example of T-shaped Zn(OC t Bu 2 Ph) 2 (THF) complex, which could not be previously synthesized using more conventional LiOR/HOR precursors. The reaction of [Ru(cymene)Cl 2 ] 2 with Tl 2 (OC t Bu 2 Ph) 2 results in the formation of a ruthenium( ii ) alkoxide complex. For ruthenium, the initial coordination of the alkoxide triggers C–H activation at the ortho -H of [OC t Bu 2 Ph] which results in its bidentate coordination. In addition to Tl 2 (OC t Bu 2 Ph) 2 , related Tl 2 (OC t Bu 2 (3,5-Me 2 C 6 H 3 )) 2 was also synthesized, characterized, and shown to exhibit similar reactivity with iron and ruthenium precursors. Synthetic, structural, and spectroscopic characterizations are presented.more » « less